critical-opalescence

Critical Opalescence Skill

"At the critical point, the fluid becomes opalescent—milky white—because density fluctuations occur at all scales, scattering light of all wavelengths."

Overview

Critical opalescence is the dramatic increase in light scattering near a phase transition's critical point. It's the visual signature of criticality.

System	Critical Point	Observable
CO₂	31°C, 73 atm	Milky fluid
Binary mixtures	Consolute point	Turbidity divergence
Proteins	Folding transition	Aggregate scattering
Ising model	T_c (Onsager: 2D exact)	Correlation length → ∞

The Physics

Why Opalescence at Criticality?

Normal state:
  ξ (correlation length) ~ 1 nm
  Fluctuations small, invisible

Near critical point:
  ξ → ∞ (diverges)
  Fluctuations at ALL scales
  λ_light ~ ξ → strong scattering

At T_c:
  ξ = ∞
  Scale-free fluctuations
  Maximum opalescence

Ornstein-Zernike Theory

import numpy as np

def structure_factor(q, xi, chi_0=1.0):
    """
    Ornstein-Zernike structure factor S(q).

    S(q) = χ₀ / (1 + q²ξ²)

    Args:
        q: scattering wavevector
        xi: correlation length
        chi_0: susceptibility amplitude

    At criticality (ξ → ∞): S(q) ~ q^(-2)
    """
    return chi_0 / (1 + (q * xi) ** 2)

def correlation_length(T, T_c, xi_0=1.0, nu=0.63):
    """
    Correlation length divergence near T_c.

    ξ = ξ₀ |T - T_c|^(-ν)

    Args:
        T: temperature
        T_c: critical temperature
        xi_0: microscopic length
        nu: critical exponent (3D Ising: 0.63, mean field: 0.5)
    """
    t = abs(T - T_c) / T_c
    if t < 1e-10:
        return float('inf')
    return xi_0 * (t ** (-nu))

def scattering_intensity(wavelength, xi):
    """
    Rayleigh-Gans scattering intensity.

    I ~ ξ³ for ξ << λ
    I ~ ξ² for ξ >> λ (Porod regime)
    """
    q = 2 * np.pi / wavelength
    if xi < wavelength / 10:
        # Rayleigh regime
        return xi ** 3
    else:
        # Large fluctuations
        return xi ** 2 * structure_factor(q, xi)

Connection to Onsager

Lars Onsager's exact solution of the 2D Ising model (1944) gave the first rigorous calculation of critical behavior:

Onsager's Results:
─────────────────
Critical temperature: k_B T_c / J = 2 / ln(1 + √2) ≈ 2.269

Specific heat: C ~ |T - T_c|^(-α)  with α = 0 (log divergence)
Magnetization: M ~ |T - T_c|^β    with β = 1/8
Susceptibility: χ ~ |T - T_c|^(-γ) with γ = 7/4
Correlation length: ξ ~ |T - T_c|^(-ν) with ν = 1

The 2D Ising model is EXACTLY SOLVABLE.
Opalescence would occur if we could "see" spin fluctuations.

Connection to Kolmogorov-Onsager-Hurst

┌─────────────────────────────────────────────────────────────────────┐
│              CRITICALITY ACROSS DOMAINS                             │
├─────────────────────────────────────────────────────────────────────┤
│                                                                     │
│  KOLMOGOROV        ONSAGER           HURST          OPALESCENCE    │
│  (Turbulence)      (Phase Trans)     (Memory)       (Scattering)   │
│  ─────────────     ─────────────     ──────────     ─────────────  │
│  E(k) ~ k^(-5/3)   ξ ~ |t|^(-ν)      H = 1/3        I ~ ξ^d        │
│  Scale-free        Divergence        Long-range     All wavelengths│
│  Inertial range    Critical point    Persistence    Milky white    │
│                                                                     │
│  ─────────────────── UNIFYING THEME ──────────────────────────────  │
│                                                                     │
│  SCALE INVARIANCE: No characteristic length/time at criticality    │
│  UNIVERSALITY: Same exponents for different systems                 │
│  FLUCTUATIONS: Correlations extend to all scales                    │
│                                                                     │
└─────────────────────────────────────────────────────────────────────┘

Protein Folding Connection

Proteins exhibit critical-like behavior:

def protein_scattering(concentration, T, T_fold, radius_gyration=3.0):
    """
    Light scattering from protein solutions near folding transition.

    Near T_fold:
      - Molten globule state
      - Large fluctuations
      - Increased scattering

    Aggregation (misfolding):
      - Amyloid formation
      - Massive scattering (visible turbidity)
      - Opalescence in diseased states
    """
    xi = correlation_length(T, T_fold, xi_0=radius_gyration, nu=0.5)

    # Concentration-dependent scattering
    # Zimm equation for polymers
    I = concentration * xi ** 2

    return I

class FoldingLandscape:
    """
    Energy landscape for protein folding.

    Funnel topology with roughness:
      - Native state at bottom (global minimum)
      - Kinetic traps (local minima)
      - Chaperones smooth the landscape
    """

    def __init__(self, roughness=0.3, funnel_depth=10.0):
        self.roughness = roughness  # Local trap depth
        self.funnel_depth = funnel_depth  # Global bias

    def energy(self, q):
        """
        Energy as function of folding coordinate q ∈ [0, 1].
        q = 0: unfolded
        q = 1: native
        """
        # Funnel: linear bias toward native
        funnel = -self.funnel_depth * q

        # Roughness: random traps
        traps = self.roughness * np.sin(20 * np.pi * q)

        return funnel + traps

    def folding_rate(self, T):
        """
        Kramers rate over roughened landscape.
        """
        # Effective barrier reduced by funnel
        barrier = self.roughness * self.funnel_depth ** 0.5
        return np.exp(-barrier / T)

Opalescence Types

Type	Cause	Scale	Example
Critical	ξ → ∞ at T_c	All scales	CO₂ critical point
Rayleigh	Particles << λ	~1-10 nm	Blue sky, colloids
Mie	Particles ~ λ	100-1000 nm	Clouds, milk
Tyndall	Particles > λ	1-10 μm	Fog, suspensions

Structural Color (No Pigment)

Opalescence is related to structural coloration:

Photonic crystals:
  - Periodic structure with spacing ~ λ
  - Bragg diffraction → color selection
  - Examples: opals, butterfly wings, peacock feathers

The color depends on GEOMETRY, not chemistry.
Same principle as critical opalescence: interference at specific scales.

GF(3) Integration

Trit: 0 (ERGODIC/Coordinator)

Critical opalescence is the BRIDGE between:
  - Microscopic fluctuations (atomic/molecular)
  - Macroscopic observables (turbidity, color)

GF(3) Triads:
  kolmogorov-onsager-hurst (-1) ⊗ critical-opalescence (0) ⊗ protein-folding (+1) = 0 ✓
  bifurcation-generator (-1) ⊗ critical-opalescence (0) ⊗ phase-transition (+1) = 0 ✓
  structural-stability (-1) ⊗ critical-opalescence (0) ⊗ symmetry-breaking (+1) = 0 ✓

Practical Applications

1. Detecting Phase Transitions

def detect_critical_point(T_array, scattering_array):
    """
    Find T_c from scattering data.
    Maximum scattering ≈ critical point.
    """
    idx = np.argmax(scattering_array)
    T_c = T_array[idx]

    # Fit ξ ~ |T - T_c|^(-ν) to extract ν
    # ...

    return T_c

2. Protein Aggregation Monitoring

Early detection of amyloid formation via light scattering.

3. Quality Control

Colloid stability, emulsion breakdown, crystallization.

References

1. Onsager, L. (1944). "Crystal statistics. I. A two-dimensional model with an order-disorder transition." Physical Review.
2. Stanley, H.E. (1971). Introduction to Phase Transitions and Critical Phenomena.
3. Ornstein, L.S. & Zernike, F. (1914). "Accidental deviations of density and opalescence at the critical point."
4. Anfinsen, C.B. (1973). "Principles that govern the folding of protein chains." Science.

Invocation

/critical-opalescence

Analyze systems for critical behavior via scattering signatures.